Cas:5132-30-9 BMOE: A Short-Spacer Homobifunctional Crosslinker for Sulfhydryl Mapping

1,2-Bis(maleimido)ethane (BMOE) is a widely used homobifunctional sulfhydryl-reactive crosslinker designed for high-precision protein conjugation and structural biology research. Featuring two highly reactive maleimide groups connected by a short spacer arm, BMOE selectively reacts with thiol groups in cysteine residues, forming stable thioether bonds.

Property

Specification

Product Name

1,2-Bis(maleimido)ethane

Abbreviation

BMOE

CAS Number

5132-30-9

Molecular Formula

C10H8N2O4

Molecular Weight

220.18

Purity (HPLC)

≥ 98%

MDL Number

MFCD00005517

Reactive Group

Maleimide

Spacer Arm

8.0 Å

Solubility

Soluble in DMSO or DMF


Due to its short spacer length of approximately 8 Å, BMOE is particularly valuable in studies requiring accurate mapping of close-range protein–protein interactions. This property makes it an essential reagent in chemical biology, proteomics, structural biology, and drug discovery research.

Finetech Industry Limited supplies high-purity BMOE for research applications, supporting laboratories, biotech companies, and pharmaceutical developers worldwide.

Chemical and Structural Characteristics

BMOE is designed to provide high specificity and controlled crosslinking between sulfhydryl-containing biomolecules.

Key structural features include:

Two maleimide reactive groups targeting thiol groups in proteins
Homobifunctional crosslinker design
Short spacer arm (~8 Å) enabling precise interaction mapping
Stable thioether bond formation
Efficient reaction under mild physiological conditions

The short spacer arm allows researchers to detect protein interactions occurring at very close molecular distances, improving structural interpretation in biochemical studies.

Key Applications of BMOE
1. Protein–Protein Interaction Mapping

One of the most important applications of BMOE crosslinker is the investigation of protein–protein interactions (PPIs).

Because of its short crosslinking distance, BMOE allows scientists to:

Identify direct contact sites between proteins
Confirm protein complex formation
Map interaction interfaces

This approach is commonly used in crosslinking mass spectrometry (XL-MS) experiments.

2. Structural Biology and Protein Conformation Studies

BMOE is widely used in structural biology research to study the spatial organization of proteins.

By crosslinking nearby cysteine residues, researchers can:

Determine distance constraints within protein complexes
Analyze conformational changes in proteins
Support cryo-EM and X-ray crystallography modeling

Short-range crosslinkers like BMOE provide valuable structural data for protein folding and interaction studies.

3. Antibody and Protein Conjugation

BMOE is also used in bioconjugation chemistry to create stable protein conjugates.

Applications include:

Antibody–protein conjugation
Enzyme immobilization
Biosensor development
Targeted labeling of cysteine residues

The thiol-specific reactivity of BMOE allows controlled conjugation without modifying other amino acid residues.

4. Chemical Biology and Drug Discovery Research

In pharmaceutical research, BMOE supports studies such as:

Target validation
Protein complex analysis
Screening interaction inhibitors
Mechanistic studies of signaling pathways

By stabilizing transient protein interactions, BMOE helps researchers better understand drug targets and biological pathways.

Advantages of Using BMOE

Compared with longer spacer crosslinkers, BMOE offers several important advantages:

High spatial precision

The ~8 Å spacer length enables detection of very close molecular interactions.

Selective thiol reactivity

Maleimide groups react specifically with cysteine residues, minimizing non-specific reactions.

Stable crosslink formation

BMOE forms irreversible thioether bonds that remain stable under physiological conditions.

Compatibility with multiple analytical techniques

It is compatible with:

Mass spectrometry
SDS-PAGE analysis
Structural modeling
Proteomics workflows
Finetech Industry Limited – Reliable Supplier of BMOE

Finetech Industry Limited is committed to supplying high-quality research chemicals for laboratories worldwide. Our 1,2-Bis(maleimido)ethane is manufactured under strict quality control to ensure:

High purity
Consistent batch quality
Reliable analytical data
Fast global shipping

We support researchers in chemical biology, proteomics, and pharmaceutical development with dependable reagent supply.

Conclusion

1,2-Bis(maleimido)ethane (BMOE) is a powerful thiol-reactive crosslinking reagent widely used in modern biochemical research. Its short spacer arm, high specificity, and stable crosslinking capability make it an ideal tool for investigating protein interactions, structural biology, and bioconjugation applications.

With reliable quality and professional service, Finetech Industry Limited provides BMOE to support cutting-edge research across the life sciences.